Lithium Element Properties

Complete reference for Lithium (Li, element 3): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

3 Li 6.941

Lithium

Alkali Metal — Period 2, Group 1

Atomic Identity

Atomic Number
3
Z
Symbol
Li
Standard Atomic Wt.
6.941 u
IUPAC 2021
Period
2
Group
1
IA
Block
s-block
CAS Number
7439-93-2
Li
Discovery
Johan A. Arfwedson
1817
First Isolated
William T. Brande
1821

Electron Configuration

Full notation 1s² 2s¹
Noble gas shorthand [He] 2s¹
Electrons per shell 2, 1
Valence electrons 1
Unpaired electrons 1
Spin multiplicity 2 (doublet)
Orbital Diagram
1s
2s
3 electrons (1 unpaired in 2s)
Paramagnetic

One unpaired electron in 2s

Isotopes of Lithium

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Lithium-6 ⁶Li 3 3 6.01512289 7.59% Stable
Lithium-7 ⁷Li 3 4 7.01600344 92.41% Stable
Lithium-8 ⁸Li 3 5 8.02248624 Radioactive Unstable
β⁻ decay, t½ = 840.3 ms
Lithium-9 ⁹Li 3 6 9.02679019 Radioactive Unstable
β⁻ decay, t½ = 178.3 ms

Physical Properties

State at STP Solid (metal)
Color Silvery-white
Luster Metallic
Density (25 °C) 0.534 g/cm³
Melting Point 180.54 °C (453.69 K)
Boiling Point 1342 °C (1615 K)
Heat of Fusion 3.00 kJ/mol
Heat of Vaporization 136 kJ/mol
Specific Heat (25 °C) 24.860 J/(mol·K)
Thermal Conductivity 84.8 W/(m·K)
Electrical Resistivity 92.8 nΩ·m (20 °C)
Hardness (Mohs) 0.6
Speed of Sound 6000 m/s (20 °C)

Chemical Properties

Electronegativity (Pauling) 0.98
Electron Affinity 59.6 kJ/mol
1st Ionization Energy 520.2 kJ/mol
2nd Ionization Energy 7298.1 kJ/mol
3rd Ionization Energy 11815.0 kJ/mol
Covalent Radius 128 pm
Ionic Radius (Li⁺) 76 pm
Van der Waals Radius 182 pm
Oxidation States +1 (dominant), −1 (rare)
Reactivity Reacts with water and air
Magnetic Ordering Paramagnetic
Standard Electrode Potential −3.04 V (Li⁺/Li)

Ground State Quantum Numbers

Principal (n) 2 (valence electron)
Azimuthal (l) 0 (s orbital)
Magnetic (mₗ) 0
Spin (mₛ)
Term symbol ²S₁/₂
Degeneracy 2 (doublet ground state)

Notable Emission Lines

670.78 nm (D-line)
Red (doublet)
610.36 nm
Orange-red
497.17 nm
Blue-green
460.29 nm
Blue
323.27 nm
UV (near-UV)

Lithium produces a distinctive crimson-red flame in a flame test, primarily from the 670.78 nm doublet transition.

Key Facts About Lithium

Lightest Metal

At 0.534 g/cm³, lithium is the least dense metal and the least dense solid element at standard conditions. It is light enough to float on water — though it reacts vigorously with it.

Battery Technology

Lithium has the highest electrochemical potential of any element (−3.04 V), making it essential for rechargeable lithium-ion batteries that power phones, laptops, and electric vehicles.

Crimson Flame Test

Lithium compounds burn with a bright crimson-red flame, one of the most distinctive of all the alkali metals. This property is used to identify lithium in qualitative analysis.

Medicinal Use

Lithium carbonate and lithium citrate are mood-stabilizing medications prescribed for bipolar disorder. Lithium is one of the few elements with an established role in psychiatric medicine.

Nuclear Applications

Lithium-6 is used in thermonuclear weapons as lithium deuteride and in tritium production. Lithium-7 is used as a pH buffer in pressurized water reactors in nuclear power plants.

Big Bang Nucleosynthesis

Along with hydrogen and helium, lithium was synthesized in the first few minutes after the Big Bang. Observed stellar lithium abundances provide important tests of cosmological models.

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Summary

Complete reference for Lithium (Li, element 3): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and quantum numbers.
  3. Review the isotopes table for lithium-6 and lithium-7 data including natural abundance.
  4. Consult the physical properties panel for melting point, density, and state at STP.
  5. Use the chemical properties section to understand alkali metal behavior and ionization energies.
  6. Copy any value with one click for use in reports or calculations.

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Last updated: 2026-05-28 · Reviewed by Nham Vu