Boron Element Properties

Complete reference for Boron (B, element 5): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

5 B 10.81

Boron

Metalloid — Period 2, Group 13

Atomic Identity

Atomic Number
5
Z
Symbol
B
Standard Atomic Wt.
10.81 u
IUPAC 2021
Period
2
Group
13
IIIA
Block
p-block
CAS Number
7440-42-8
B
Discovery
Davy; Gay-Lussac & Thénard
1808
Name Origin
Arabic "buraq"
Borax

Electron Configuration

Full notation 1s² 2s² 2p¹
Noble gas shorthand [He] 2s² 2p¹
Electrons per shell 2, 3
Valence electrons 3
Unpaired electrons 1
Spin multiplicity 2 (doublet)
Orbital Diagram
1s
2s
2p
5 electrons — one unpaired 2p electron
Paramagnetic

One unpaired 2p electron — weakly paramagnetic

Isotopes of Boron

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Boron-8 ⁸B 5 3 8.02461 Radioactive Unstable
β⁺ decay, t½ = 770 ms
Boron-10 ¹⁰B 5 5 10.01294 19.9% Stable
Boron-11 ¹¹B 5 6 11.00931 80.1% Stable
Boron-12 ¹²B 5 7 12.01435 Radioactive Unstable
β⁻ decay, t½ = 20.2 ms
Boron-13 ¹³B 5 8 13.01779 Radioactive Unstable
β⁻ decay, t½ = 17.4 ms

Physical Properties

State at STP Solid (metalloid)
Allotropes Amorphous, alpha-rhombohedral, beta-rhombohedral
Color Black (amorphous); dark brown to black (crystalline)
Density (25 °C) 2.08 g/cm³ (amorphous); 2.46 g/cm³ (crystalline)
Melting Point 2076 °C (2349 K)
Boiling Point 3927 °C (4200 K)
Heat of Fusion 50.2 kJ/mol
Heat of Vaporization 508 kJ/mol
Specific Heat (25 °C) 11.087 J/(mol·K)
Thermal Conductivity 27.4 W/(m·K)
Hardness (Mohs) 9.5 (crystalline)
Electrical Resistivity ~1×10⁶ Ω·m (amorphous, semiconductor)

Chemical Properties

Electronegativity (Pauling) 2.04
Electron Affinity 26.7 kJ/mol
1st Ionization Energy 800.6 kJ/mol
2nd Ionization Energy 2427.1 kJ/mol
3rd Ionization Energy 3659.7 kJ/mol
4th Ionization Energy 25025.8 kJ/mol
Covalent Radius 84 pm
Ionic Radius (B³⁺) 27 pm
Van der Waals Radius 192 pm
Oxidation States +3 (dominant), +1, 0
Magnetic Ordering Diamagnetic (bulk)
Crystal Structure Rhombohedral (alpha & beta allotropes)

Ground State Quantum Numbers

Principal (n) 2 (valence electrons)
Azimuthal (l) 1 (p orbital)
Magnetic (mₗ) −1, 0, or +1
Spin (mₛ) +½ (single unpaired electron)
Term symbol ²P₁/₂
Degeneracy 2 (doublet ground state)

Notable Emission Lines

182.64 nm
Far UV
249.68 nm
UV (deep)
249.77 nm
UV (deep)
345.10 nm
UV (near)
412.20 nm
Violet

Boron produces a distinctive bright green flame in a flame test due to the volatile methyl borate formed when trace moisture is present. Its strongest spectroscopic lines lie in the ultraviolet range.

Key Facts About Boron

Electron-Deficient Lewis Acid

Boron has only three valence electrons and forms three bonds in most compounds, leaving an empty p orbital. This makes boron compounds (like BF₃ and BCl₃) strong Lewis acids that readily accept electron pairs. This property is central to boron's role in organocatalysis and synthesis.

Neutron Capture in Nuclear Engineering

Boron-10 has a thermal neutron absorption cross-section of approximately 3,840 barns — among the highest of any stable nuclide. Control rods made from boron carbide (B₄C) and borated water systems are critical safety components in nuclear reactors worldwide.

Extreme Hardness

Boron carbide (B₄C) has a Vickers hardness exceeding 30 GPa, making it the third-hardest known material after diamond and cubic boron nitride (c-BN). It is used in ballistic armor, abrasive grinding wheels, and nuclear shielding. Cubic boron nitride rivals diamond in hardness for industrial cutting tools.

Essential Plant Micronutrient

Boron is an essential micronutrient for plants; it stabilizes cell walls and is critical for pollen germination, fruit development, and sugar transport. Boron deficiency causes "hollow heart" in beets and stunted growth in many crops. Borax is widely used in agriculture as a boron fertilizer supplement.

Boron Neutron Capture Therapy (BNCT)

BNCT is a cancer treatment that selectively delivers boron-10 compounds to tumor cells. When irradiated with thermal neutrons, the ¹⁰B(n,α)⁷Li reaction releases high-energy alpha particles that destroy the tumor cell from within while largely sparing surrounding healthy tissue.

Borax and Industrial Chemistry

Borax (Na₂B₄O₇·10H₂O) is one of the oldest known boron compounds. It serves as a flux in metallurgy, a cleaning agent, a fire retardant, and a precursor to borosilicate glass (Pyrex). The Mojave Desert's Death Valley and Turkey's Kirka mine are the world's largest borax deposits.

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Summary

Complete reference for Boron (B, element 5): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and quantum numbers.
  3. Review the isotopes table for boron-10 and boron-11 data including natural abundance.
  4. Consult the physical properties panel for melting point, density, and state at STP.
  5. Use the chemical properties section to understand metalloid behavior and ionization energies.
  6. Copy any value with one click for use in reports or calculations.

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Last updated: 2026-05-28 · Reviewed by Nham Vu