Helium Element Properties

Complete reference for Helium (He, element 2): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

2 He 4.003

Helium

Noble Gas — Period 1, Group 18

Atomic Identity

Atomic Number
2
Z
Symbol
He
Standard Atomic Wt.
4.002602 u
IUPAC 2021
Period
1
Group
18
VIIIA
Block
s-block
CAS Number
7440-59-7
He
Discovery
Pierre Janssen & Norman Lockyer
1868 (solar)
First Isolated
William Ramsay
1895 (Earth)

Electron Configuration

Full notation 1s²
Noble gas shorthand [He] (defines the noble gas core)
Electrons per shell 2
Valence electrons 2
Unpaired electrons 0
Spin multiplicity 1 (singlet)
Orbital Diagram
1s
2 electrons (paired)
Diamagnetic

No unpaired electrons

Isotopes of Helium

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Helium-3 ³He 2 1 3.01602932265 0.000134% Stable
Helium-4 ⁴He 2 2 4.00260325413 99.999866% Stable
Helium-6 ⁶He 2 4 6.01888589 Radioactive Unstable
β⁻ decay, t½ = 806.7 ms
Helium-8 ⁸He 2 6 8.03393439 Radioactive Unstable
β⁻ decay, t½ = 119.1 ms

Physical Properties

State at STP Gas
Color Colorless
Odor Odorless
Density (gas, 0 °C) 0.1785 g/L
Density (liquid) 0.125 g/cm³ (at bp)
Melting Point None (does not solidify at 1 atm)
Boiling Point −268.93 °C (4.22 K)
Critical Temperature −267.96 °C (5.19 K)
Critical Pressure 0.227 MPa
Heat of Vaporization 0.0829 kJ/mol
Specific Heat (gas) 20.786 J/(mol·K)
Thermal Conductivity 0.1513 W/(m·K)
Speed of Sound (gas) 972 m/s (0 °C)

Chemical Properties

Electronegativity (Pauling) N/A (noble gas)
Electron Affinity < 0 (negative)
1st Ionization Energy 2372.3 kJ/mol
2nd Ionization Energy 5250.5 kJ/mol
Covalent Radius 28 pm
Van der Waals Radius 140 pm
Oxidation States 0 (standard)
Reactivity Essentially inert
Magnetic Ordering Diamagnetic
Molar Volume 22,400 cm³/mol (STP)
Known Compounds None (standard conditions)
Flammability Non-flammable

Ground State Quantum Numbers

Principal (n) 1
Azimuthal (l) 0 (s orbital)
Magnetic (mₗ) 0
Spin (mₛ) +½ and −½ (paired)
Term symbol ¹S₀
Degeneracy 1 (singlet ground state)

Notable Emission Lines

587.56 nm (D3)
Yellow
667.82 nm
Red
706.52 nm
Deep red
447.15 nm
Violet-blue
492.19 nm
Blue-green
501.57 nm
Green

These lines were first observed in the solar spectrum in 1868, leading to helium’s discovery before it was found on Earth.

Key Facts About Helium

Second Most Abundant

Helium is the second most abundant element in the universe (~24% by mass), but extremely rare on Earth where it escapes into space.

Lowest Boiling Point

At 4.22 K (−268.93 °C), helium has the lowest boiling point of any element and is the only substance that does not solidify at normal pressure.

Superfluid Helium-4

Below 2.17 K, liquid ⁴He becomes a superfluid with zero viscosity, flowing through microscopic pores and climbing container walls spontaneously.

MRI & Cryogenics

Liquid helium cools the superconducting magnets in MRI machines to near absolute zero, enabling strong magnetic fields without electrical resistance.

Solar Origin

Helium was discovered in 1868 from solar spectral lines before ever being found on Earth. Its name comes from Helios, the Greek god of the Sun.

Fusion Product

Helium-4 is produced in stars by hydrogen fusion and in Earth's crust by alpha decay of radioactive elements such as uranium and thorium.

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Summary

Complete reference for Helium (He, element 2): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and quantum numbers.
  3. Review the isotopes table for helium-3 and helium-4 data including natural abundance.
  4. Consult the physical properties panel for boiling point, density, and state at STP.
  5. Use the chemical properties section to understand the noble gas behavior and ionization energies.
  6. Copy any value with one click for use in reports or calculations.

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Last updated: 2026-05-28 · Reviewed by Nham Vu