Sodium Element Properties

Complete reference for Sodium (Na, element 11): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

11 Na 22.990

Sodium

Alkali Metal — Period 3, Group 1

Atomic Identity

Atomic Number
11
Z
Symbol
Na
Natrium
Standard Atomic Wt.
22.9898 u
IUPAC 2021
Period
3
Group
1
IA
Block
s-block
CAS Number
7440-23-5
Na
Discovery
Humphry Davy
1807
Named from
Natrium (Latin)
natron

Electron Configuration

Full notation 1s² 2s² 2p⁶ 3s¹
Noble gas shorthand [Ne] 3s¹
Electrons per shell 2, 8, 1
Valence electrons 1
Unpaired electrons 1
Spin multiplicity 2 (doublet)
Orbital Diagram
1s
2s
2p
3s
11 electrons (1 unpaired in 3s)
Paramagnetic

One unpaired electron in 3s

Key Isotopes of Sodium

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Sodium-22 ²²Na 11 11 21.9944364 Radioactive Unstable
β⁺ decay, t½ = 2.6019 yr
Sodium-23 ²³Na 11 12 22.9897693 100% Stable
Sodium-24 ²⁴Na 11 13 23.9909629 Radioactive Unstable
β⁻ decay, t½ = 14.957 hr
Sodium-25 ²⁵Na 11 14 24.9899540 Radioactive Unstable
β⁻ decay, t½ = 59.1 s

Sodium-23 is the only stable isotope. Sodium-24 is used in medical and industrial tracing applications due to its convenient half-life.

Physical Properties

State at STP Solid (metal)
Color Silvery-white
Luster Metallic
Density (25 °C) 0.968 g/cm³
Melting Point 97.72 °C (370.87 K)
Boiling Point 882.9 °C (1156.1 K)
Heat of Fusion 2.60 kJ/mol
Heat of Vaporization 97.42 kJ/mol
Specific Heat (25 °C) 28.230 J/(mol·K)
Thermal Conductivity 142 W/(m·K)
Electrical Resistivity 47.7 nΩ·m (20 °C)
Hardness (Mohs) 0.5
Speed of Sound 3200 m/s (20 °C)

Chemical Properties

Electronegativity (Pauling) 0.93
Electron Affinity 52.8 kJ/mol
1st Ionization Energy 495.8 kJ/mol
2nd Ionization Energy 4562.4 kJ/mol
3rd Ionization Energy 6910.3 kJ/mol
Covalent Radius 166 pm
Ionic Radius (Na⁺) 102 pm
Van der Waals Radius 227 pm
Oxidation States +1 (dominant), −1 (rare)
Reactivity Vigorous with water and O₂
Magnetic Ordering Paramagnetic
Standard Electrode Potential −2.71 V (Na⁺/Na)

Ground State Quantum Numbers

Principal (n) 3 (valence electron)
Azimuthal (l) 0 (s orbital)
Magnetic (mℓ) 0
Spin (mₛ)
Term symbol ²S₁/₂
Degeneracy 2 (doublet ground state)

Notable Emission Lines

588.995 nm (D₂ line)
Yellow-orange
589.592 nm (D₁ line)
Yellow-orange
568.82 nm
Yellow-green
498.28 nm
Blue-green
330.24 nm
UV (near-UV)

Sodium produces an intense yellow-orange flame, dominated by the famous sodium D-line doublet at 589 nm — one of the most recognizable spectral signatures in chemistry.

Common Sodium Compounds

Compound Formula Common Name Key Uses
Sodium chloride NaCl Table salt Food seasoning, food preservation, de-icing roads, chlorine production
Sodium hydroxide NaOH Lye / caustic soda Soap making, paper production, drain cleaners, chemical manufacturing
Sodium bicarbonate NaHCO₃ Baking soda Baking leavener, antacid, fire extinguisher, odor neutralizer
Sodium carbonate Na₂CO₃ Washing soda Glass manufacturing, water softening, laundry detergent
Sodium hypochlorite NaOCl Bleach Disinfection, water treatment, fabric whitening
Sodium nitrate NaNO₃ Chile saltpeter Fertilizers, food preservative, explosives, glass making
Sodium sulfate Na₂SO₄ Glauber's salt Detergents, glass manufacturing, textile dyeing
Sodium acetate CH₃COONa Hot ice Food flavoring (salt and vinegar), heating pads, textile dyeing

Key Facts About Sodium

Essential for Life

Sodium ions (Na⁺) are critical for nerve impulse transmission, muscle contraction, and regulating fluid balance in the body. Cells maintain a sodium-potassium gradient using the Na⁺/K⁺-ATPase pump, consuming about 30% of the body's resting energy.

Yellow Flame Test

Sodium produces the most intense and recognizable yellow-orange flame of any element, caused by the 589 nm D-line doublet. Even trace amounts of sodium overwhelm other colors, making it both a useful analytical tool and a challenge when testing other metals.

Sixth Most Abundant

Sodium is the sixth most abundant element in Earth's crust at about 2.6% by mass, found mainly in minerals such as halite (rock salt), albite, and natron. The oceans contain roughly 1.08 kg of sodium per liter of seawater.

Street Lighting

Low-pressure sodium (LPS) vapor lamps emit the characteristic monochromatic yellow 589 nm light and were widely used for street lighting because of their exceptional energy efficiency. High-pressure sodium (HPS) lamps produce a broader golden-white light still common in road lighting.

Discovered by Electrolysis

Humphry Davy isolated sodium in 1807 by passing electricity through molten sodium hydroxide, the first time a reactive metal was isolated this way. He named it sodium from the English word soda; Berzelius coined the symbol Na from natrium.

Softer than Most Metals

With a Mohs hardness of only 0.5, sodium can be cut with a kitchen knife. Freshly cut surfaces are shiny and silvery-white but quickly tarnish to dull gray as they react with oxygen and moisture in the air, forming sodium oxide and sodium hydroxide.

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Summary

Complete reference for Sodium (Na, element 11): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and quantum numbers.
  3. Review the isotopes table for sodium-23 and other isotopes including natural abundance.
  4. Consult the physical properties panel for melting point, density, and state at STP.
  5. Use the chemical properties section to understand alkali metal behavior and ionization energies.
  6. Explore common sodium compounds and their everyday applications.

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Last updated: 2026-05-28 · Reviewed by Nham Vu