Silicon Element Properties

Complete reference for Silicon (Si, element 14): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

14 Si 28.085

Silicon

Metalloid — Period 3, Group 14

Atomic Identity

Atomic Number
14
Z
Symbol
Si
Standard Atomic Wt.
28.085 u
IUPAC 2021
Period
3
Group
14
IVA
Block
p-block
CAS Number
7440-21-3
Si
Discovery
Jöns J. Berzelius
1823
Named By
Berzelius
Latin: silicis

Electron Configuration

Full notation 1s² 2s² 2p⁶ 3s² 3p²
Noble gas shorthand [Ne] 3s² 3p²
Electrons per shell 2, 8, 4
Valence electrons 4
Unpaired electrons 2
Spin multiplicity 3 (triplet)
Orbital Diagram (3p)
3s
3p
2 unpaired electrons in 3p (Hund's rule)
Paramagnetic

2 unpaired electrons

Isotopes of Silicon

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Silicon-28 ²⁸Si 14 14 27.9769265325 92.223% Stable
Silicon-29 ²⁹Si 14 15 28.9764946649 4.685% Stable
Silicon-30 ³⁰Si 14 16 29.973770136 3.092% Stable
Silicon-32 ³²Si 14 18 31.97415154 Trace Unstable
Radioactive — β⁻, t½ = 153 yr

Physical Properties

State at STP Solid
Appearance Blue-grey lustrous solid
Crystal Structure Diamond cubic
Density 2.329 g/cm³ (at 25 °C)
Melting Point 1414 °C (1687 K)
Boiling Point 3265 °C (3538 K)
Heat of Fusion 50.21 kJ/mol
Heat of Vaporization 383 kJ/mol
Specific Heat Capacity 19.789 J/(mol·K)
Thermal Conductivity 149 W/(m·K)
Electrical Resistivity 2.3×10³ Ω·m (intrinsic)
Mohs Hardness 6.5

Chemical Properties

Electronegativity (Pauling) 1.90
Electron Affinity 134.068 kJ/mol
1st Ionization Energy 786.5 kJ/mol
2nd Ionization Energy 1577.1 kJ/mol
3rd Ionization Energy 3231.6 kJ/mol
4th Ionization Energy 4355.5 kJ/mol
Covalent Radius 111 pm
Van der Waals Radius 210 pm
Oxidation States +4, +2, −4
Band Gap (300 K) 1.12 eV
Electron Mobility ~1400 cm²/(V·s)
Hole Mobility ~450 cm²/(V·s)

Ground State Quantum Numbers

Principal (n) 3 (valence shell)
Azimuthal (l) 1 (p orbital, valence)
Magnetic (mℓ) 0, +1 (two half-filled)
Spin (m‑) +½ each (Hund's rule)
Term symbol ³P₀
Ground state config [Ne] 3s² 3p²

Abundance & Nuclear Data

Earth's crust (mass) 27.7% (2nd most abundant)
Universe (mass fraction) 6.5×10⁻⁴
Ocean (mg/L) ~2.2 mg/L
Human body (ppm) ~18 ppm (by mass)
Nuclear spin (²⁹Si) I = ½
NMR frequency (²⁹Si) 79.50 MHz at 9.4 T

Key Facts About Silicon

Second Most Abundant Element

Silicon makes up about 27.7% of Earth's crust by mass, making it the second most abundant element after oxygen.

Semiconductor Foundation

Silicon's 1.12 eV band gap and excellent oxide formation (SiO₂) make it the cornerstone of modern microelectronics and computing.

Solar Energy

Crystalline silicon accounts for over 90% of all solar photovoltaic panels installed worldwide, converting sunlight directly into electricity.

Silicate Minerals

Silicon dioxide (SiO₂) and silicate minerals form the bulk of Earth's crust. Quartz, feldspar, mica, and clay minerals are all silicates.

High Melting Point

Silicon melts at 1414 °C, much higher than most metals, which enables its use in high-temperature applications and as a refractory material.

Silicon Carbide

SiC (carborundum) is nearly as hard as diamond (Mohs 9.5) and is used as an abrasive, in high-power electronics, and in electric vehicle inverters.

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Summary

Complete reference for Silicon (Si, element 14): atomic data, electron configuration, isotopes, physical constants, and chemical behavior.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and quantum numbers.
  3. Review the isotopes table for stable silicon isotopes including natural abundances.
  4. Consult the physical properties panel for melting point, boiling point, density, and state at STP.
  5. Use the chemical properties section to understand reactivity, oxidation states, and electronegativity.
  6. Copy any value with one click for use in reports or calculations.

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Last updated: 2026-05-28 · Reviewed by Nham Vu