Magnesium Element Properties

Complete reference for Magnesium (Mg, element 12): atomic data, electron configuration, isotopes, physical constants, and unit converter.

12 Mg 24.305

Magnesium

Alkaline Earth Metal — Period 3, Group 2

Solid at STP Diamagnetic s-block

Atomic Identity

Atomic Number
12
Z
Symbol
Mg
Magnesium
Standard Atomic Wt.
24.305 u
IUPAC 2021
Period
3
Group
2
IIA
Block
s-block
CAS Number
7439-95-4
Mg
Discovery
Joseph Black
1755
Isolation
Humphry Davy
1808

Periodic Table Locator — Period 3 Neighborhood

11
Na
Sodium
Group 1
12
Mg
Magnesium
Group 2
13
Al
Aluminum
Group 13
14
Si
Silicon
Group 14
15
P
Phosphorus
Group 15
16
S
Sulfur
Group 16
17
Cl
Chlorine
Group 17
18
Ar
Argon
Group 18

Magnesium (Z=12) sits between sodium (alkali metal) and aluminum (post-transition metal) in Period 3. It is directly below beryllium (Z=4) and above calcium (Z=20) in Group 2.

Electron Configuration

Full notation 1s² 2s² 2p⁶ 3s²
Noble gas shorthand [Ne] 3s²
Electrons per shell 2, 8, 2
Valence electrons 2
Unpaired electrons 0
Magnetic ordering Diamagnetic
Spin multiplicity 1 (singlet)
Orbital Diagram
1s
2s
2p
3s
12 electrons (all paired)
Diamagnetic

No unpaired electrons — all orbitals filled

Key Isotopes of Magnesium

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Magnesium-23 ²³Mg 12 11 22.9941242 Radioactive Unstable
β⁺ decay, t½ = 11.317 s
Magnesium-24 ²⁴Mg 12 12 23.9850417 78.99% Stable
Magnesium-25 ²⁵Mg 12 13 24.9858370 10.00% Stable
Magnesium-26 ²⁶Mg 12 14 25.9825930 11.01% Stable
Magnesium-27 ²⁷Mg 12 15 26.9843407 Radioactive Unstable
β⁻ decay, t½ = 9.458 min
Magnesium-28 ²⁸Mg 12 16 27.9838768 Radioactive Unstable
β⁻ decay, t½ = 20.915 hr

Magnesium has three stable isotopes (Mg-24, Mg-25, Mg-26). Mg-26 is used in geochemistry to trace magnesium cycling; Mg-28 is used in medical research as a tracer isotope.

Physical Properties

State at STP Solid (metal)
Color Silvery-white
Luster Metallic
Density (25 °C) 1.738 g/cm³
Melting Point 650 °C (923 K)
Boiling Point 1090 °C (1363 K)
Heat of Fusion 8.48 kJ/mol
Heat of Vaporization 128 kJ/mol
Specific Heat (25 °C) 24.869 J/(mol·K)
Thermal Conductivity 156 W/(m·K)
Electrical Resistivity 43.9 nΩ·m (20 °C)
Hardness (Mohs) 2.5
Crystal Structure Hexagonal close-packed (hcp)

Chemical Properties

Electronegativity (Pauling) 1.31
Electron Affinity 0 kJ/mol (endothermic)
1st Ionization Energy 737.7 kJ/mol
2nd Ionization Energy 1450.7 kJ/mol
3rd Ionization Energy 7732.7 kJ/mol
Covalent Radius 141 pm
Ionic Radius (Mg²⁺) 72 pm
Van der Waals Radius 173 pm
Oxidation States +2 (dominant), +1 (rare)
Reactivity Moderate; burns in air and CO₂
Magnetic Ordering Diamagnetic
Standard Electrode Potential −2.372 V (Mg²⁺/Mg)

Ground State Quantum Numbers

Principal (n) 3 (valence electrons)
Azimuthal (l) 0 (s orbital)
Magnetic (mℓ) 0
Spin (mₛ) +½ and −½ (paired)
Term symbol ¹S₀
Degeneracy 1 (singlet ground state)

Notable Emission Lines

285.21 nm
UV (near-UV)
383.82 nm
Violet
448.11 nm
Blue
516.73 nm
Green
517.27 nm
Green
518.36 nm
Green

Magnesium produces a brilliant white flame. Its emission spectrum shows prominent lines in the UV and green regions; the 285.21 nm line is widely used in atomic absorption spectroscopy for magnesium analysis.

Property Unit Converter

Convert common Magnesium property values between units. Enter a value and select the conversion.

Temperature
Celsius 650.00 °C
Kelvin 923.15 K
Fahrenheit 1202.00 °F
Density
g/cm³ 1.738 g/cm³
kg/m³ 1738.00 kg/m³
lb/ft³ 108.51 lb/ft³
Energy (per mol)
kJ/mol 737.70 kJ/mol
eV/atom 7.646 eV
kcal/mol 176.33 kcal/mol

Common Magnesium Compounds

Compound Formula Common Name Key Uses
Magnesium oxide MgO Magnesia / periclase Refractory materials, antacid, nutritional supplement, fertilizer
Magnesium hydroxide Mg(OH)₂ Milk of magnesia Antacid, laxative, wastewater treatment, fire retardant
Magnesium sulfate MgSO₄ Epsom salt Muscle relaxant baths, fertilizer, laxative, dyeing textiles
Magnesium chloride MgCl₂ Magnesium chloride De-icing roads, dust control, food additive (tofu coagulant)
Magnesium carbonate MgCO₃ Magnesite Refractory bricks, antacid, chalk substitute for gymnastics
Magnesium nitrate Mg(NO₃)₂ Magnesium nitrate Fertilizers, pyrotechnics, catalyst, desiccant
Magnesium silicate Mg₂SiO₄ Forsterite / talc Ceramics, insulation, cosmetics (talcum powder)
Chlorophyll C₅₅H₇₂MgN₄O₅ Chlorophyll a Photosynthesis pigment in all green plants and algae

Key Facts About Magnesium

Chlorophyll Central Atom

Every molecule of chlorophyll — the pigment powering photosynthesis in all green plants and algae — has a single Mg²⁺ ion at its center, chelated by a porphyrin ring. Without magnesium, plants cannot synthesize chlorophyll and eventually turn yellow, a symptom known as chlorosis.

Burns in CO₂ and N₂

Magnesium is one of the few elements that burns in carbon dioxide (Mg + CO₂ → MgO + C) and nitrogen (3 Mg + N₂ → Mg₃N₂). This makes standard CO₂ fire extinguishers ineffective and even dangerous on magnesium fires. Class D extinguishers using dry sand or special powder must be used instead.

Lightest Structural Metal

At 1.738 g/cm³, magnesium is the lightest structural metal used in engineering — about 35% lighter than aluminum and 78% lighter than iron. Magnesium alloys are extensively used in aerospace, automotive, and consumer electronics for weight-critical components.

Essential Biological Role

Magnesium is the fourth most abundant mineral in the human body and is required by over 300 enzyme systems. It is critical for ATP synthesis (all ATP in cells is complexed as Mg-ATP), DNA and RNA synthesis, protein synthesis, and regulation of nerve and muscle function.

Eighth Most Abundant

Magnesium is the eighth most abundant element in Earth's crust (~2.1% by mass). It is the third most abundant element dissolved in seawater (~1272 mg/L). Major mineral sources include magnesite (MgCO₃), dolomite (CaMg(CO₃)₂), and olivine (Mg₂SiO₄).

History and Name

Magnesium was recognized as an element by Joseph Black in 1755. Humphry Davy first isolated magnesium metal in 1808 by electrolysis. The name derives from Magnesia, a region of Greece (modern Thessaly) where magnesium-containing minerals were found; it shares this etymology with manganese and magnet.

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Summary

Complete reference for Magnesium (Mg, element 12): atomic data, electron configuration, isotopes, physical constants, and unit converter.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and quantum numbers.
  3. Review the isotopes table for stable and notable radioactive isotopes including natural abundances.
  4. Consult the physical and chemical properties panels for melting point, density, ionization energies, and more.
  5. Use the interactive unit converter to convert magnesium property values between common units.
  6. Explore the mini periodic table locator to visualize where magnesium sits among neighboring elements.

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Last updated: 2026-05-28 · Reviewed by Nham Vu