Scandium Element Properties

Complete reference for Scandium (Sc, element 21): atomic data, electron configuration, isotopes, physical constants, and unit converter.

21 Sc 44.956

Scandium

Transition Metal — Period 4, Group 3

Solid at STP Paramagnetic d-block

Atomic Identity

Atomic Number
21
Z
Symbol
Sc
Scandium
Standard Atomic Wt.
44.955908 u
IUPAC 2021
Period
4
Group
3
IIIB
Block
d-block
CAS Number
7440-20-2
Sc
Discovery
Lars Fredrik Nilson
1879
Name Origin
Latin: Scandia (Scandinavia)

Periodic Table Locator — Period 4 Neighborhood

19
K
Potassium
Group 1
20
Ca
Calcium
Group 2
21
Sc
Scandium
Group 3
22
Ti
Titanium
Group 4
23
V
Vanadium
Group 5
39
Y
Yttrium
Period 5
57
La
Lanthanum
Period 6

Scandium (Z=21) is the first d-block transition metal in Period 4, sitting between calcium (alkaline earth metal) and titanium. It is directly above yttrium (Z=39) in Group 3 and is sometimes grouped with the rare earth elements in industry despite not being a lanthanide.

Electron Configuration

Full notation 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹ 4s²
Noble gas shorthand [Ar] 3d¹ 4s²
Electrons per shell 2, 8, 9, 2
Valence electrons 3 (1 in 3d, 2 in 4s)
Unpaired electrons 1
Magnetic ordering Paramagnetic
Spin multiplicity 2 (doublet)
Simplified Orbital Diagram
1s
2e
2s
2e
2p
6e
3s
2e
3p
6e
3d
1e
4s
2e
21 electrons total (1 unpaired in 3d)
Paramagnetic

One unpaired 3d electron — weakly attracted to magnetic fields

Key Isotopes of Scandium

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Scandium-44 ⁴⁴Sc 21 23 43.9594010 Radioactive Unstable
β⁺/EC decay, t½ = 3.97 h
Scandium-45 ⁴⁵Sc 21 24 44.9559119 100% Stable
Scandium-46 ⁴⁶Sc 21 25 45.9551719 Radioactive Unstable
β⁻ decay, t½ = 83.79 d
Scandium-47 ⁴⁷Sc 21 26 46.9524075 Radioactive Unstable
β⁻ decay, t½ = 3.349 d
Scandium-48 ⁴⁸Sc 21 27 47.9522236 Radioactive Unstable
β⁻ decay, t½ = 43.67 h

Scandium is monoisotopic — all naturally occurring scandium is Sc-45. Sc-46 (t½ = 83.79 d) is the most commercially important radioisotope, used as a radioactive tracer in oil refinery cracking processes and hydrology. Sc-44 and Sc-47 are investigated for targeted radionuclide therapy in oncology.

Physical Properties

State at STP Solid (metal)
Color Silvery-white
Luster Metallic (yellows slightly in air)
Density (20 °C) 2.985 g/cm³
Melting Point 1541 °C (1814 K)
Boiling Point 2836 °C (3109 K)
Heat of Fusion 14.1 kJ/mol
Heat of Vaporization 332.7 kJ/mol
Specific Heat (25 °C) 25.52 J/(mol·K)
Thermal Conductivity 15.8 W/(m·K)
Electrical Resistivity 562 nΩ·m (20 °C)
Hardness (Mohs) ~2.5 (estimated)
Crystal Structure Hexagonal close-packed (hcp) at RT

Chemical Properties

Electronegativity (Pauling) 1.36
Electron Affinity 18 kJ/mol
1st Ionization Energy 633.1 kJ/mol
2nd Ionization Energy 1235.0 kJ/mol
3rd Ionization Energy 2388.6 kJ/mol
4th Ionization Energy 7090.6 kJ/mol
Covalent Radius 170 pm
Ionic Radius (Sc³⁺) 74.5 pm (6-coord.)
Van der Waals Radius 211 pm
Oxidation States +3 (dominant), +2, +1
Reactivity Moderate; tarnishes in air
Magnetic Ordering Paramagnetic

Ground State Quantum Numbers

Principal (n) 3 (valence 3d) / 4 (4s)
Azimuthal (l) 2 (d orbital, valence 3d)
Magnetic (mℓ) −2 to +2 (five d orbitals)
Spin (mₛ) +½ (unpaired 3d electron)
Term symbol ²D₃⁄₂
Degeneracy 4 (doublet D state)

Notable Emission Lines

335.37 nm
UV/Violet
357.63 nm
UV/Violet
363.07 nm
Violet
391.18 nm
Violet
402.04 nm
Violet-blue
424.68 nm
Violet-blue
604.98 nm
Orange

Scandium has a rich emission spectrum used in metal halide arc lamps, producing light with a spectral distribution close to sunlight (CRI > 90). The 391 nm line is used in atomic absorption spectroscopy for scandium quantification.

Property Unit Converter

Convert common Scandium property values between units. Enter a value and select the conversion.

Temperature
Celsius 1541.00 °C
Kelvin 1814.15 K
Fahrenheit 2805.80 °F
Density
g/cm³ 2.9850 g/cm³
kg/m³ 2985.00 kg/m³
lb/ft³ 186.38 lb/ft³
Energy (per mol)
kJ/mol 633.10 kJ/mol
eV/atom 6.5610 eV
kcal/mol 151.32 kcal/mol

Common Scandium Compounds

Compound Formula Common Name Key Uses
Scandium oxide Sc₂O₃ Scandia High-temperature ceramics, electronic substrates, stabilized zirconia dopant, optical coatings
Scandium chloride ScCl₃ Scandium trichloride Synthesis intermediate; Lewis acid catalyst precursor; starting material for metalorganic Sc chemistry
Scandium triflate Sc(OTf)₃ Scandium(III) triflate Powerful water-stable Lewis acid catalyst for Diels-Alder, Friedel-Crafts, and aldol reactions in organic synthesis
Scandium iodide ScI₃ Scandium triiodide Additive in metal halide arc lamps to produce high-CRI daylight-spectrum lighting
Scandium fluoride ScF₃ Scandium trifluoride Negative thermal expansion material; nuclear applications; optical fiber components
Scandium nitrate Sc(NO₃)₃ Scandium(III) nitrate Analytical reagent; precursor for sol-gel scandium oxide coatings
Scandium carbide Sc₂C Scandium carbide Component in endohedral fullerenes (Sc₂C₂@C₈₄); hard ceramic research
Aluminum scandium Al-Sc alloy Sc-modified aluminum Aerospace structural parts, high-performance bicycle frames, lacrosse sticks, baseball bats

Key Facts About Scandium

First d-block Transition Metal

Scandium (Z=21) is the first element in the d-block, marking the start of the transition metals in Period 4. Its single 3d electron distinguishes it from the s-block alkaline earth metals. Despite this, scandium behaves more like aluminum in its chemistry due to its almost exclusive +3 oxidation state and the small, highly charged Sc³⁺ ion.

Predicted by Mendeleev

Dmitri Mendeleev predicted the existence of scandium in 1871, calling it "ekaboron" and forecasting its atomic mass (~44 u), density (~3.0 g/cm³), and oxide formula (Sc₂O₃). Lars Fredrik Nilson discovered the element in 1879 in the minerals euxenite and gadolinite, and Per Teodor Cleve recognized it as Mendeleev's predicted element — a landmark validation of the periodic law.

Remarkable Alloy Strengthener

Adding just 0.1–0.5% scandium to aluminum creates an alloy with dramatically improved strength, hardness, and resistance to heat and corrosion. Sc pins grain boundaries during welding, preventing the softening that normally occurs in heat-affected zones. The resulting Al-Sc alloys rival titanium in specific strength while being lighter, and are used in MIG-welded aerospace structures, bicycle frames, and sports equipment.

Sunlight-Quality Arc Lamps

Scandium iodide (ScI₃) is the key additive in metal halide arc lamps used in sports stadiums, film studios, and theatrical lighting. The ScI₃ broadens the emission spectrum of mercury arc lamps to closely mimic natural daylight, achieving a color rendering index (CRI) above 90. This application consumes a significant fraction of the world's annual scandium production.

Negative Thermal Expansion in ScF₃

Scandium trifluoride (ScF₃) is one of only a handful of materials that shrinks when heated over a wide temperature range (from near absolute zero to over 1000 K). This unusual negative thermal expansion (NTE) behavior arises from transverse vibrational modes in its rigid ReO₃-type crystal structure. ScF₃ is studied for thermal management composites and precision engineering components where dimensional stability over temperature is critical.

Critical Mineral for Solid Oxide Fuel Cells

Scandium-stabilized zirconia (ScSZ) — typically 9–11 mol% Sc₂O₃ in ZrO₂ — has the highest known ionic conductivity among oxide ion conductors at 700–800 °C, roughly 3–5× higher than the more common yttria-stabilized zirconia (YSZ). ScSZ electrolytes allow solid oxide fuel cells (SOFCs) to operate at lower temperatures, extending stack lifetimes and reducing system costs. This makes scandium a strategically important mineral for clean energy infrastructure.

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Summary

Complete reference for Scandium (Sc, element 21): atomic data, electron configuration, isotopes, physical constants, and unit converter.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and quantum numbers.
  3. Review the isotopes table for stable and notable radioactive isotopes with natural abundances.
  4. Consult the physical and chemical properties panels for melting point, density, ionization energies, and more.
  5. Use the interactive unit converter to convert scandium property values between common units.
  6. Explore the mini periodic table locator to visualize where scandium sits among neighboring elements.

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Last updated: 2026-05-28 · Reviewed by Nham Vu