Calcium Element Properties

Complete reference for Calcium (Ca, element 20): atomic data, electron configuration, isotopes, physical constants, and unit converter.

20 Ca 40.078

Calcium

Alkaline Earth Metal — Period 4, Group 2

Solid at STP Diamagnetic s-block

Atomic Identity

Atomic Number
20
Z
Symbol
Ca
Calcium
Standard Atomic Wt.
40.078 u
IUPAC 2021
Period
4
Group
2
IIA
Block
s-block
CAS Number
7440-70-2
Ca
Discovery
Humphry Davy
1808
Name Origin
Latin: calx (lime)

Periodic Table Locator — Period 4 Neighborhood (s-block)

19
K
Potassium
Group 1
20
Ca
Calcium
Group 2
21
Sc
Scandium
Group 3
12
Mg
Magnesium
Period 3
38
Sr
Strontium
Period 5
56
Ba
Barium
Period 6

Calcium (Z=20) sits between potassium (alkali metal) and scandium (transition metal) in Period 4. It is directly below magnesium (Z=12) and above strontium (Z=38) in Group 2.

Electron Configuration

Full notation 1s² 2s² 2p⁶ 3s² 3p⁶ 4s²
Noble gas shorthand [Ar] 4s²
Electrons per shell 2, 8, 8, 2
Valence electrons 2
Unpaired electrons 0
Magnetic ordering Diamagnetic
Spin multiplicity 1 (singlet)
Simplified Orbital Diagram
1s
2e
2s
2e
2p
6e
3s
2e
3p
6e
4s
2e
20 electrons total (all paired)
Diamagnetic

No unpaired electrons — all orbitals filled

Key Isotopes of Calcium

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Calcium-40 ⁴⁰Ca 20 20 39.9625909 96.941% Stable
Calcium-41 ⁴¹Ca 20 21 40.9622779 Trace/Cosmo. Unstable
Electron capture, t½ = 99,400 yr
Calcium-42 ⁴²Ca 20 22 41.9586176 0.647% Stable
Calcium-43 ⁴³Ca 20 23 42.9587662 0.135% Stable
Calcium-44 ⁴⁴Ca 20 24 43.9554816 2.086% Stable
Calcium-46 ⁴⁶Ca 20 26 45.9536890 0.004% Stable
Calcium-47 ⁴⁷Ca 20 27 46.9545414 Radioactive Unstable
β⁻ decay, t½ = 4.536 d
Calcium-48 ⁴⁸Ca 20 28 47.9525228 0.187% Unstable
ββ decay, t½ ≫ 4×10¹⁹ yr

Calcium-40 accounts for ~97% of natural calcium. Ca-41 (cosmogenic) is used to date bone ages. Ca-47 is a medical tracer for calcium metabolism studies. Ca-48 is a near-doubly-magic nucleus used in nuclear physics research and neutrinoless double-beta decay experiments.

Physical Properties

State at STP Solid (metal)
Color Silvery-white
Luster Metallic (tarnishes pale yellow in air)
Density (20 °C) 1.55 g/cm³
Melting Point 842 °C (1115 K)
Boiling Point 1484 °C (1757 K)
Heat of Fusion 8.54 kJ/mol
Heat of Vaporization 154.7 kJ/mol
Specific Heat (25 °C) 25.929 J/(mol·K)
Thermal Conductivity 201 W/(m·K)
Electrical Resistivity 33.6 nΩ·m (20 °C)
Hardness (Mohs) 1.75
Crystal Structure Face-centered cubic (fcc) at RT

Chemical Properties

Electronegativity (Pauling) 1.00
Electron Affinity −186 kJ/mol (unstable Ca⁻)
1st Ionization Energy 589.8 kJ/mol
2nd Ionization Energy 1145.4 kJ/mol
3rd Ionization Energy 4912.4 kJ/mol
Covalent Radius 176 pm
Ionic Radius (Ca²⁺) 100 pm (6-coord.)
Van der Waals Radius 231 pm
Oxidation States +2 (dominant), +1 (exotic)
Reactivity Moderate; tarnishes in air
Magnetic Ordering Diamagnetic
Standard Electrode Potential −2.868 V (Ca²⁺/Ca)

Ground State Quantum Numbers

Principal (n) 4 (valence electrons)
Azimuthal (l) 0 (s orbital)
Magnetic (mℓ) 0
Spin (mₛ) +½ and −½ (paired)
Term symbol ¹S₀
Degeneracy 1 (singlet ground state)

Notable Emission Lines

393.37 nm
Violet
396.85 nm
Violet
422.67 nm
Violet-blue
430.25 nm
Blue
558.19 nm
Yellow-green
616.22 nm
Orange-red
643.91 nm
Red

Calcium produces a characteristic brick-red to orange flame in a flame test. The 422.67 nm resonance line is widely used in atomic absorption spectroscopy (AAS) for calcium analysis.

Property Unit Converter

Convert common Calcium property values between units. Enter a value and select the conversion.

Temperature
Celsius 842.00 °C
Kelvin 1115.15 K
Fahrenheit 1547.60 °F
Density
g/cm³ 1.5500 g/cm³
kg/m³ 1550.00 kg/m³
lb/ft³ 96.76 lb/ft³
Energy (per mol)
kJ/mol 589.80 kJ/mol
eV/atom 6.1131 eV
kcal/mol 141.02 kcal/mol

Common Calcium Compounds

Compound Formula Common Name Key Uses
Calcium carbonate CaCO₃ Limestone / chalk / marble Cement, glass, antacid (Tums), toothpaste, paper filler
Calcium oxide CaO Quicklime Cement production, steel slag treatment, water treatment
Calcium hydroxide Ca(OH)₂ Slaked lime / limewater Mortar, plaster, soil pH adjustment, water softening
Calcium sulfate CaSO₄·2H₂O Gypsum Drywall (plasterboard), plaster of Paris, soil conditioner
Calcium phosphate Ca₃(PO₄)₂ Tricalcium phosphate Bone and teeth mineral, fertilizer, food supplement
Calcium chloride CaCl₂ Calcium chloride De-icing roads, food additive (E509), desiccant, concrete accelerant
Calcium fluoride CaF₂ Fluorite / fluorspar Optical lenses, UV windows, HF production, steel flux
Calcium silicate Ca₂SiO₄ Belite Portland cement clinker, fireproofing, calcium silicate board

Key Facts About Calcium

Most Abundant Mineral in the Body

Calcium is the most abundant mineral in the human body by mass — about 1 kg in an average adult. Approximately 99% is stored as hydroxyapatite in bones and teeth. The remaining 1% in blood and cells governs muscle contraction, nerve transmission, hormone release, and blood clotting via intracellular Ca²⁺ signaling.

Foundation of Cement and Concrete

Limestone (CaCO₃) is the primary raw material for Portland cement, the most widely used construction material on Earth. Heating limestone produces quicklime (CaO), which reacts with water to form slaked lime Ca(OH)₂. When combined with silicates in cement clinker, calcium silicate hydrate phases form the binding matrix of concrete.

Fifth Most Abundant in Earth's Crust

At ~3.6% of Earth's crust by mass, calcium is the fifth most abundant element overall (after oxygen, silicon, aluminum, and iron) and the most abundant alkaline earth metal. It occurs naturally as calcite, aragonite (both CaCO₃), gypsum (CaSO₄·2H₂O), fluorite (CaF₂), and dolomite (CaMg(CO₃)₂).

Strongly Reducing Metal

With a standard electrode potential of −2.868 V, calcium is a powerful reducing agent — more reactive than magnesium but less than sodium. It reduces most metal oxides and halides at high temperature, making it useful for producing refractory metals such as thorium, uranium, and chromium by thermite-style metallothermic reduction.

Brick-Red Flame Test

Calcium gives a distinctive brick-red (orange-red) flame in the flame test, a simple but reliable qualitative test used to identify Ca²⁺ ions. The color arises from the 616 nm and 622 nm emission lines of electronically excited calcium atoms. This property is also exploited in red signal flares and some firework formulations.

Isolated by Electrolysis

Calcium was first isolated in 1808 by Humphry Davy using electrolysis of a calcium mercury amalgam, the same year he isolated strontium, barium, and magnesium. The name comes from the Latin calx, meaning lime — the material (calcium oxide) known and used since antiquity for mortar and plaster.

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Summary

Complete reference for Calcium (Ca, element 20): atomic data, electron configuration, isotopes, physical constants, and unit converter.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and quantum numbers.
  3. Review the isotopes table for stable and notable radioactive isotopes with natural abundances.
  4. Consult the physical and chemical properties panels for melting point, density, ionization energies, and more.
  5. Use the interactive unit converter to convert calcium property values between common units.
  6. Explore the mini periodic table locator to visualize where calcium sits among neighboring elements.

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Last updated: 2026-05-28 · Reviewed by Nham Vu