Oxygen Element Properties

Complete reference for Oxygen (O, element 8): atomic data, electron configuration with interactive shell diagram, isotopes, physical constants, and a temperature unit toggle.

8 O 15.999

Oxygen

Nonmetal — Period 2, Group 16

Atomic Identity

Atomic Number
8
Z
Symbol
O
Standard Atomic Wt.
15.999 u
IUPAC 2021
Period
2
Group
16 (Chalcogens)
VIA
Block
p-block
Category
Nonmetal (diatomic)
CAS Number
7782-44-7
O₂ gas
Discovery
Carl W. Scheele, 1771
Also Joseph Priestley 1774

Electron Configuration

Full notation 1s² 2s² 2p⁴
Noble gas shorthand [He] 2s² 2p⁴
Electrons per shell 2, 6
Valence electrons 6
Unpaired electrons 2
Spin multiplicity 3 (triplet)
Orbital Diagram
1s
2s
2p
8 electrons — 2 unpaired in 2p (triplet ground state)
Paramagnetic

Two unpaired electrons — triplet ground state (³P₂)

Physical Properties

State at STP Gas (colorless)
Density (gas, STP) 1.429 g/L
Melting Point -218.79 °C
Boiling Point -182.96 °C
Critical Temperature -118.56 °C (154.59 K)
Critical Pressure 5.043 MPa
Heat of Vaporization 6.82 kJ/mol
Heat of Fusion 0.444 kJ/mol
Molar Heat Capacity 29.378 J/(mol·K)
Thermal Conductivity 26.58 mW/(m·K)
Crystal Structure (solid) Cubic (alpha form)
Color Colorless (pale blue liq.)

Isotopes of Oxygen

Isotope Symbol Protons Neutrons Mass (u) Natural Abundance Stability
Oxygen-15 ¹⁵O 8 7 15.00307 Radioactive Unstable
β⁺ decay, t½ = 122.24 s
Oxygen-16 ¹⁶O 8 8 15.99491 99.757% Stable
Oxygen-17 ¹⁷O 8 9 16.99913 0.038% Stable
Oxygen-18 ¹⁸O 8 10 17.99916 0.205% Stable
Oxygen-19 ¹⁹O 8 11 19.00358 Radioactive Unstable
β⁻ decay, t½ = 26.91 s

Oxygen-16 (¹⁶O) is a doubly magic nucleus (8 protons and 8 neutrons fill complete nuclear shells), making it exceptionally stable. Oxygen-18 (¹⁸O) is used in paleoclimatology — the ¹⁸O/¹⁶O ratio in ice cores and foraminifera shells reveals past ocean temperatures and ice volumes.

Chemical Properties

Electronegativity (Pauling) 3.44
Electron Affinity 141.0 kJ/mol
1st Ionization Energy 1313.9 kJ/mol
2nd Ionization Energy 3388.3 kJ/mol
3rd Ionization Energy 5300.5 kJ/mol
Oxidation States -2, -1, 0, +1, +2
Common oxidation state -2 (most oxides, water)
O=O Bond Energy 498 kJ/mol
Magnetic Ordering Paramagnetic (O₂ molecule)

Atomic Properties

Covalent Radius 66 pm
Van der Waals Radius 152 pm
Ionic Radius (O²⁻) 140 pm
Atomic Radius (empirical) 60 pm
O–O single bond length 148 pm (H₂O₂)
O=O double bond length 121 pm (O₂)
O–H bond length (water) 96 pm
Ground State Term Symbol ³P₂
Number of Energy Levels 2

Key Facts About Oxygen

Atmospheric Abundance

Molecular oxygen (O₂) constitutes approximately 20.95% of Earth's dry atmosphere by volume. Nearly all of this oxygen is of biogenic origin — produced by photosynthesis over approximately 2.4 billion years. The Great Oxidation Event (~2.4 Ga) fundamentally transformed Earth's surface chemistry.

Essential for Aerobic Life

Oxygen serves as the terminal electron acceptor in aerobic cellular respiration. Mitochondria use O₂ to oxidize glucose, producing ATP, CO₂, and water. Approximately 90% of the energy used by aerobic organisms comes from O₂-dependent metabolism. It is also a structural component of water (H₂O), making up nearly 89% of water by mass.

Ozone Layer (O₃)

In the stratosphere (15–35 km altitude), oxygen forms ozone (O₃) that absorbs 97–99% of the Sun's harmful ultraviolet radiation (UV-B and UV-C). Without this shield, most surface life would be destroyed by UV damage to DNA. Chlorofluorocarbons (CFCs) catalytically destroy ozone, leading to the Montreal Protocol (1987).

Steel & Industrial Production

The basic oxygen furnace (BOF) uses pure O₂ blown into molten iron to remove carbon and impurities, producing steel. This process accounts for about 70% of global steel production. LOX (liquid oxygen) is also used in rocket propulsion as a powerful oxidizer paired with liquid hydrogen or RP-1 kerosene in engines like SpaceX's Merlin.

Most Abundant Element in Crust

Oxygen is the most abundant element by mass in Earth's crust (approximately 46%), in the hydrosphere (~89% by mass as water), and in the human body (~65% by mass). As silicates and oxides, oxygen bonds dominate rock-forming minerals — quartz (SiO₂), feldspars, olivine, and carbonates all rely on O²⁻ anions.

Reactive Oxygen Species (ROS)

Partially reduced oxygen species — superoxide (O₂⁻·), hydrogen peroxide (H₂O₂), hydroxyl radical (·OH), and singlet oxygen (¹O₂) — are collectively called reactive oxygen species. ROS play dual roles: at low levels they act as signaling molecules; at high levels they cause oxidative stress, damaging DNA, proteins, and lipids. Antioxidants (vitamins C and E, superoxide dismutase) counter ROS damage.

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Summary

Complete reference for Oxygen (O, element 8): atomic data, electron configuration with interactive shell diagram, isotopes, physical constants, and a temperature unit toggle.

How it works

  1. Browse the atomic identity section for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and the interactive shell diagram.
  3. Toggle the temperature unit (°C / °F / K) on the physical properties card to convert melting and boiling points.
  4. Review the isotopes table for oxygen-16, oxygen-17, and oxygen-18 data including natural abundance.
  5. Consult the chemical properties panel for electronegativity, ionization energies, and oxidation states.
  6. Explore the key facts section for biological roles, industrial applications, and atmospheric significance.

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Last updated: 2026-05-28 · Reviewed by Nham Vu