Indium Electron Configuration
Reference for indium's electron configuration ([Kr] 4d¹⁰ 5s² 5p¹), orbital box diagram, valence electron count, and key atomic data for In (Z=49).
Indium — Electron Configuration
Atomic number 49 · Post-transition metal · Period 5, Group 13 · p-block
Group 13 / p-block — First Electron into 5p
Indium (Z=49) is the first Period 5 element to place an electron in the 5p subshell. Its configuration [Kr] 4d¹⁰ 5s² 5p¹ follows straightforward Aufbau filling — no anomalies unlike its neighbor silver (Z=47). The single 5p¹ electron is the valence electron that distinguishes indium's chemistry from cadmium's.
Subshell Breakdown
| Subshell | Type | Electrons | Max Capacity | Notation |
|---|---|---|---|---|
| 1s | s orbital, shell n=1 | 2 | 2 | 1s² |
| 2s | s orbital, shell n=2 | 2 | 2 | 2s² |
| 2p | p orbitals, shell n=2 | 6 | 6 | 2p⁶ |
| 3s | s orbital, shell n=3 | 2 | 2 | 3s² |
| 3p | p orbitals, shell n=3 | 6 | 6 | 3p⁶ |
| 3d | d orbitals, shell n=3 | 10 | 10 | 3d¹⁰ |
| 4s | s orbital, shell n=4 | 2 | 2 | 4s² |
| 4p | p orbitals, shell n=4 | 6 | 6 | 4p⁶ |
| 4d | d orbitals, shell n=4 | 10 | 10 | 4d¹⁰ |
| 5s | s orbital, shell n=5 | 2 | 2 | 5s² |
| 5p | p orbitals, shell n=5 (valence) | 1 | 6 | 5p¹ |
| Total | 49 | |||
Full Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p¹
All 11 subshells written explicitly.
Noble-Gas Shorthand
[Kr] 4d¹⁰ 5s² 5p¹
[Kr] = 1s²…4p⁶ (krypton core, Z=36, 36 electrons).
Valence Electrons
5s² 5p¹ (3 total)
All 3 lost → In³⁺. Rarely In⁺ (loses 5p¹ only).
Shell Fill Summary
Shell 5 can hold up to 50 electrons (5s + 5p + 5d + 5f + 5g). Indium uses 3 slots — 5s² and one of the three 5p orbitals — leaving the 5p subshell mostly empty.
Group 13 — Same s² p¹ Valence Pattern
| Element | Z | Configuration | Common Ion |
|---|---|---|---|
| Boron (B) | 5 | [He] 2s² 2p¹ | B³⁺ (covalent) |
| Aluminum (Al) | 13 | [Ne] 3s² 3p¹ | Al³⁺ |
| Gallium (Ga) | 31 | [Ar] 3d¹⁰ 4s² 4p¹ | Ga³⁺ |
| Indium (In) | 49 | [Kr] 4d¹⁰ 5s² 5p¹ | In³⁺ |
| Thallium (Tl) | 81 | [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p¹ | Tl³⁺ / Tl⁺ |
All Group 13 elements share the ns² np¹ valence pattern. Thallium also forms Tl⁺ because the relativistic inert-pair effect stabilizes the 6s² pair, an effect absent for indium.
Summary
Reference for indium's electron configuration ([Kr] 4d¹⁰ 5s² 5p¹), orbital box diagram, valence electron count, and key atomic data for In (Z=49).
How it works
- The Aufbau principle fills subshells from lowest to highest energy in order: 1s → 2s → 2p → 3s → 3p → 4s → 3d → 4p → 5s → 4d → 5p.
- Indium has 49 electrons, one more than cadmium (Z=48). The 49th electron enters the 5p subshell.
- The noble-gas core [Kr] accounts for the first 36 electrons (1s² through 4p⁶).
- Beyond the krypton core, 10 electrons fill the 4d subshell and 3 fill the 5th shell (5s² 5p¹).
- Noble-gas notation: [Kr] 4d¹⁰ 5s² 5p¹ — [Kr] replaces the filled inner shells through krypton.
- Indium's 3 valence electrons (5s² 5p¹) are in shell n=5; losing all three gives In³⁺.
Use cases
- Quick reference for chemistry homework on post-transition metals and Group 13 electron filling.
- Understand why indium has 3 valence electrons and forms In³⁺ in most compounds.
- Visualize the orbital filling for Period 5 p-block elements using the orbital box diagram.
- Compare indium to aluminum and thallium — its Group 13 neighbors above and below.
- Teaching aid for Aufbau principle, Hund's rule, and periodic table trends in Period 5.
- Learn how the 5p¹ configuration relates to indium's role in ITO and semiconductor applications.
- Verify quantum numbers for the outermost subshells of indium.