Copper Element Properties

Complete reference for copper (Cu, element 29): atomic data, electron configuration, isotopes, physical constants, oxidation states, and a property unit converter.

29 Cu 63.546

Copper

Transition Metal — Period 4, Group 11

Solid at STP Diamagnetic d-block

Atomic Identity

Atomic Number
29
Z
Symbol
Cu
Latin: cuprum
Standard Atomic Wt.
63.546 u
IUPAC 2021
Period
4
Group
11
I B
Block
d-block
CAS Number
7440-50-8
Cu
Discovery
Prehistoric
~8000 BCE (use)
Name Origin
Latin: cuprum
From Cyprus (Kypros)

Periodic Table Locator — Period 4 Neighborhood (d-block)

28
Ni
Nickel
Group 10
29
Cu
Copper
Group 11
30
Zn
Zinc
Group 12
47
Ag
Silver
Period 5
79
Au
Gold
Period 6

Copper (Z=29) sits between nickel (Z=28) and zinc (Z=30) in Period 4. It is directly below silver (Z=47) and above gold (Z=79) in Group 11 of the d-block — the coinage metals triad.

Electron Configuration

Full notation 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s¹
Noble gas shorthand [Ar] 3d¹⁰ 4s¹
Electrons per shell 2, 8, 18, 1
Valence electrons 11 (3d¹⁰ 4s¹)
Unpaired electrons 1 (in 4s)
Magnetic ordering Diamagnetic
Anomaly Expected [Ar] 3d⁹ 4s² — full 3d¹⁰ is more stable
Term symbol ²S₁/₂
Simplified Orbital Diagram
1s
2s
2p
3s
3p
3d
10e
4s
1e
29 electrons total — 3d fully filled, 4s singly occupied
Anomalous Config

Full 3d¹⁰ stabilizes the atom — 4s has only 1 electron

Key Isotopes of Copper

Isotope Symbol Protons Neutrons Mass (u) Abundance Stability
Copper-63 ⁶³Cu 29 34 62.9295975 69.17% Stable
Copper-64 ⁶⁴Cu 29 35 63.9297642 Radioactive Unstable
β⁺/β⁻, EC; t½ = 12.70 h — PET imaging tracer
Copper-65 ⁶⁵Cu 29 36 64.9277895 30.83% Stable
Copper-67 ⁶⁷Cu 29 38 66.9277303 Radioactive Unstable
β⁻ decay; t½ = 61.83 h — cancer therapy

Copper has only two stable isotopes, Cu-63 and Cu-65. Cu-64 is a clinically important radioisotope used in PET imaging and targeted cancer radiotherapy due to its favorable half-life and dual beta emission. Cu-67 is under active investigation as a therapeutic radioisotope for antibody-directed cancer treatment.

Physical Properties

State at STP Solid (metal)
Color Reddish-orange (distinctive)
Luster Metallic; tarnishes green (patina)
Density (20 °C) 8960 kg/m³ (8.960 g/cm³)
Melting Point 1085 °C (1358 K / 1985 °F)
Boiling Point 2562 °C (2835 K)
Heat of Fusion 13.26 kJ/mol
Heat of Vaporization 300.4 kJ/mol
Specific Heat (25 °C) 24.440 J/(mol·K)
Thermal Conductivity 401 W/(m·K)
Electrical Resistivity 16.78 nΩ·m (20 °C)
Hardness (Mohs) 3.0
Crystal Structure FCC (face-centered cubic)
Lattice Parameter a = 361.49 pm

Chemical Properties

Electronegativity (Pauling) 1.90
Electron Affinity 119.2 kJ/mol
1st Ionization Energy 745.5 kJ/mol
2nd Ionization Energy 1957.9 kJ/mol
3rd Ionization Energy 3555 kJ/mol
Covalent Radius 132 pm
Van der Waals Radius 140 pm
Ionic Radius (Cu⁺) 77 pm (4-coord.)
Ionic Radius (Cu²⁺) 73 pm (6-coord.)
Oxidation States 0, +1, +2 (common); +3, +4 (rare)
Reactivity Moderate; resists dilute acids
Magnetic Ordering Diamagnetic
Standard Potential (Cu²⁺/Cu) +0.3419 V
Standard Potential (Cu⁺/Cu) +0.521 V

Oxidation States of Copper

State Ion / Form Example Compound Notes
0 Cu⁰ Cu metal, Cu(CO)₄ (carbonyls) Native copper; organometallic compounds
+1 Cu⁺ (cuprous) CuCl, CuBr, Cu₂O, CuCN Stable in insoluble salts; disproportionates in solution
+2 Cu²⁺ (cupric) CuSO₄·5H₂O, CuO, CuCl₂, Cu(OH)₂ Most stable aqueous state; blue color in solution
+3 Cu(III) CuF₃, LaCuO₃ (cuprate superconductors) Found in high-temperature superconductors
+4 Cu(IV) Cs₂CuF₆ (rare) Extremely rare; only in strongly oxidizing conditions

Ground State Quantum Numbers

Principal (n) 3 (3d) / 4 (4s)
Azimuthal (l) — 3d 2 (d orbital)
Azimuthal (l) — 4s 0 (s orbital)
Magnetic (mℓ) −2 to +2 (d subshell)
Spin (mₛ) +½ (single 4s electron)
Term symbol ²S₁/₂
Spin multiplicity 2 (doublet — one unpaired)
Degeneracy 2 (J = ½)

Notable Emission Lines

324.75 nm
UV/Near-UV
327.40 nm
UV/Near-UV
510.55 nm
Green
515.32 nm
Green
521.82 nm
Green
578.21 nm
Yellow

In a flame test, copper produces a distinctive blue-green flame. The resonance lines at 324.75 nm and 327.40 nm are primary lines used in atomic absorption spectroscopy (AAS) for copper determination in environmental and industrial samples.

Property Unit Converter

Convert common copper property values between units. Enter a value and select the conversion.

Temperature
Celsius 1085.00 °C
Kelvin 1358.15 K
Fahrenheit 1985.00 °F
Density
g/cm³ 8.9600 g/cm³
kg/m³ 8960.00 kg/m³
lb/ft³ 559.44 lb/ft³
Energy (per mol)
kJ/mol 745.50 kJ/mol
eV/atom 7.7264 eV
kcal/mol 178.19 kcal/mol

Common Copper Compounds

Compound Formula Common Name Key Uses
Copper(II) sulfate pentahydrate CuSO₄·5H₂O Blue vitriol / bluestone Fungicide, electroplating, swimming pool algaecide, lab reagent
Copper(I) oxide Cu₂O Cuprite Red pigment, antifouling paint, rectifier in electronics
Copper(II) oxide CuO Black copper oxide Pigment, catalyst, Li-ion battery anode material
Copper(II) chloride CuCl₂ Copper dichloride Lewis acid catalyst, wood preservative, food coloring (E141)
Copper(I) chloride CuCl Nantokite Catalyst for Sandmeyer reactions, flame colorant
Copper(II) hydroxide Cu(OH)₂ Cupric hydroxide Fungicide (Bordeaux mixture with CaSO₄), battery electrode
Copper(II) carbonate CuCO₃ Malachite (basic form) Green pigment, copper ore mineral, art pigment
Copper(II) nitrate Cu(NO₃)₂·3H₂O Cupric nitrate Electroplating, light-sensitive coatings, wood preservative

Key Facts About Copper

Humanity's Oldest Metal

Copper artifacts date to around 8700 BCE, making it the oldest metal in recorded human use. Its occurrence as native metal (pure metallic nuggets) meant no smelting was required initially. The subsequent Chalcolithic (Copper Age) and Bronze Age (~3300–1200 BCE) defined entire civilizations. Copper axes, tools, mirrors, and coins underpinned ancient economies from Mesopotamia to the Americas.

The Coinage Metals Triad

Copper, silver, and gold form Group 11 of the periodic table and share a completed inner d-subshell. All three have been used as coinage for millennia due to their rarity, malleability, corrosion resistance, and attractive appearance. Copper's positive standard reduction potential (+0.34 V) means it does not dissolve in dilute acids, a key property that made bronze coins durable. The US penny was nearly pure copper until 1982.

World's Best Practical Conductor

Silver (Z=47) has slightly higher conductivity than copper, but copper's lower cost and higher abundance make it the de facto standard for electrical wiring. The world consumes over 25 million tonnes of copper per year, with roughly 65% used in electrical applications. A typical home contains about 45 kg of copper wiring. Electric vehicles use 3–4× more copper per vehicle than internal-combustion cars.

Green Patina: Natural Protection

When copper is exposed to air and moisture over years, it develops a green patina called verdigris — a mixture of copper carbonates, hydroxides, and sulfates (mainly Cu₂CO₃(OH)₂ malachite). Unlike iron rust, copper patina is chemically stable and forms a protective layer that actually slows further corrosion. Famous examples include the Statue of Liberty (81 tonnes of copper sheets), the British Museum roof, and many historic church domes.

Essential Trace Element in Biology

Copper is biologically essential in trace amounts. It is the active metal in hemocyanin (the oxygen carrier in many mollusks and arthropods, analogous to hemoglobin in vertebrates), cytochrome c oxidase (mitochondrial Complex IV), superoxide dismutase (antioxidant enzyme), and ceruloplasmin (copper transport protein in blood). The adult human body contains about 100 mg of copper, mostly in the liver, brain, and muscle.

Antimicrobial Copper Surfaces

Copper and its alloys exhibit oligodynamic antimicrobial activity — surfaces kill bacteria, fungi, and many viruses within 2 hours of contact. The EPA has registered over 500 copper alloys as antimicrobial. During the COVID-19 pandemic, research showed SARS-CoV-2 survived on plastic for up to 72 hours but was inactivated on copper within 4 hours. Copper door handles, railings, and hospital surfaces are increasingly deployed in healthcare settings.

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Summary

Complete reference for copper (Cu, element 29): atomic data, electron configuration, isotopes, physical constants, oxidation states, and a property unit converter.

How it works

  1. Browse the atomic identity card for symbol, atomic number, and standard atomic weight.
  2. Check the electron configuration panel for orbital notation and the anomalous [Ar] 3d¹⁰ 4s¹ arrangement.
  3. Review the isotopes table for stable and notable radioactive isotopes with natural abundances.
  4. Consult the physical and chemical properties panels for melting point, density, ionization energies, and oxidation states.
  5. Use the interactive unit converter to convert copper property values between common units.
  6. Explore the key facts section for industrial context and interesting chemistry of copper.

Use cases

  • Look up copper constants for chemistry homework, metallurgy, or materials science work.
  • Verify atomic data when writing lab reports or research papers.
  • Reference isotope data for radiochemistry or nuclear research.
  • Convert melting and boiling points between Celsius, Fahrenheit, and Kelvin.
  • Study anomalous d-block electron configurations using copper as the canonical example.
  • Confirm oxidation states (+1, +2) for writing ionic formulae or balancing redox equations.
  • Research copper compounds for industrial chemistry, biology, or environmental science.
  • Quick-reference ionization energies for electrochemistry or spectroscopy calculations.

Frequently Asked Questions

Last updated: 2026-06-18 · Reviewed by Nham Vu