Americium Electron Configuration
Reference for americium's electron configuration: [Rn] 5f⁷ 7s² (full: 1s²…6p⁶ 5f⁷ 7s²). Includes orbital filling table, shell breakdown, and why the half-filled 5f⁷ is especially stable.
Americium — Electron Configuration
Atomic number 95 · Actinide series · Period 7 · f-block
Half-Filled 5f⁷ Stability
Americium's 5f subshell holds exactly 7 electrons — one in each of the seven 5f orbitals, all with parallel spins (Hund's rule). This half-filled arrangement maximizes exchange energy, lowering the total electronic energy. The effect is the same reason manganese prefers 3d⁵ and europium prefers 4f⁷. Because 5f⁷ is already especially stable, americium has a relatively low first ionization energy and prefers the +2 and +3 oxidation states rather than promoting electrons to 6d.
Noble-Gas Shorthand
[Rn] 5f⁷ 7s²
[Rn] = 86-electron radon core.
Full Expanded Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p⁶ 5f⁷ 7s²
All 95 electrons written by subshell.
Subshell Breakdown
| Subshell | Type | Electrons | Capacity | Notation |
|---|---|---|---|---|
| 1s | s orbital, shell n=1 | 2 | 2 | 1s² |
| 2s | s orbital, shell n=2 | 2 | 2 | 2s² |
| 2p | p orbitals, shell n=2 | 6 | 6 | 2p⁶ |
| 3s | s orbital, shell n=3 | 2 | 2 | 3s² |
| 3p | p orbitals, shell n=3 | 6 | 6 | 3p⁶ |
| 3d | d orbitals, shell n=3 | 10 | 10 | 3d¹⁰ |
| 4s | s orbital, shell n=4 | 2 | 2 | 4s² |
| 4p | p orbitals, shell n=4 | 6 | 6 | 4p⁶ |
| 4d | d orbitals, shell n=4 | 10 | 10 | 4d¹⁰ |
| 4f | f orbitals, shell n=4 | 14 | 14 | 4f¹⁴ |
| 5s | s orbital, shell n=5 | 2 | 2 | 5s² |
| 5p | p orbitals, shell n=5 | 6 | 6 | 5p⁶ |
| 5d | d orbitals, shell n=5 | 10 | 10 | 5d¹⁰ |
| 6s | s orbital, shell n=6 | 2 | 2 | 6s² |
| 6p | p orbitals, shell n=6 | 6 | 6 | 6p⁶ |
| 5f | f orbitals, shell n=5 | 7 | 14 | 5f⁷ |
| 7s | s orbital, shell n=7 | 2 | 2 | 7s² |
| Total | 95 | |||
Valence subshells (5f and 7s) are highlighted. All others form the [Rn] core.
Shell Fill Summary
Summary
Reference for americium's electron configuration: [Rn] 5f⁷ 7s² (full: 1s²…6p⁶ 5f⁷ 7s²). Includes orbital filling table, shell breakdown, and why the half-filled 5f⁷ is especially stable.
How it works
- Americium's 95 electrons fill orbitals following the Aufbau principle, in order of increasing energy.
- Radon ([Rn], Z=86) provides the filled core: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p⁶.
- After the [Rn] core, the 5f sublevel fills before 6d because 5f lies lower in energy at Z=95.
- Seven electrons enter 5f — one per orbital (Hund's rule), creating a half-filled 5f⁷ arrangement with all spins parallel.
- The two remaining electrons occupy 7s², giving the ground-state configuration [Rn] 5f⁷ 7s².
- The half-filled 5f⁷ is exceptionally stable due to symmetric exchange energy, similar to Eu (Z=63) in the lanthanide row.
Use cases
- Chemistry reference for students studying actinide or transuranium element configurations.
- Understand why the half-filled 5f⁷ subshell is energetically favorable.
- Compare americium's configuration with europium ([Xe] 4f⁷ 6s²) in the lanthanide series.
- Verify quantum numbers and subshell counts for exam preparation.
- Teaching aid for periodic trends, electron shielding, and Hund's rule in f-block elements.
- Reference for nuclear chemistry and actinide series properties.