Americium Electron Configuration

Reference for americium's electron configuration: [Rn] 5f⁷ 7s² (full: 1s²…6p⁶ 5f⁷ 7s²). Includes orbital filling table, shell breakdown, and why the half-filled 5f⁷ is especially stable.

Z = 95 Am Americium

Americium — Electron Configuration

Atomic number 95 · Actinide series · Period 7 · f-block

[Rn] 5f⁷ 7s² 95 electrons 9 outer e⁻ Half-filled 5f⁷

Half-Filled 5f⁷ Stability

Americium's 5f subshell holds exactly 7 electrons — one in each of the seven 5f orbitals, all with parallel spins (Hund's rule). This half-filled arrangement maximizes exchange energy, lowering the total electronic energy. The effect is the same reason manganese prefers 3d⁵ and europium prefers 4f⁷. Because 5f⁷ is already especially stable, americium has a relatively low first ionization energy and prefers the +2 and +3 oxidation states rather than promoting electrons to 6d.

Noble-Gas Shorthand

[Rn] 5f⁷ 7s²

[Rn] = 86-electron radon core.

Full Expanded Configuration

1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p⁶ 5f⁷ 7s²

All 95 electrons written by subshell.

Subshell Breakdown

Subshell Type Electrons Capacity Notation
1s s orbital, shell n=1 2 2 1s²
2s s orbital, shell n=2 2 2 2s²
2p p orbitals, shell n=2 6 6 2p⁶
3s s orbital, shell n=3 2 2 3s²
3p p orbitals, shell n=3 6 6 3p⁶
3d d orbitals, shell n=3 10 10 3d¹⁰
4s s orbital, shell n=4 2 2 4s²
4p p orbitals, shell n=4 6 6 4p⁶
4d d orbitals, shell n=4 10 10 4d¹⁰
4f f orbitals, shell n=4 14 14 4f¹⁴
5s s orbital, shell n=5 2 2 5s²
5p p orbitals, shell n=5 6 6 5p⁶
5d d orbitals, shell n=5 10 10 5d¹⁰
6s s orbital, shell n=6 2 2 6s²
6p p orbitals, shell n=6 6 6 6p⁶
5f f orbitals, shell n=5 7 14 5f⁷
7s s orbital, shell n=7 2 2 7s²
Total 95

Valence subshells (5f and 7s) are highlighted. All others form the [Rn] core.

Shell Fill Summary

Shell 1 (n=1) — 1s² 2 / 2 electrons (100%)
Shell 2 (n=2) — 2s² 2p⁶ 8 / 8 electrons (100%)
Shell 3 (n=3) — 3s² 3p⁶ 3d¹⁰ 18 / 18 electrons (100%)
Shell 4 (n=4) — 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 32 / 32 electrons (100%)
Shell 5 (n=5) — 5s² 5p⁶ 5d¹⁰ 5f⁷ 25 / 50 electrons (50%)
Shell 6 (n=6) — 6s² 6p⁶ 8 / 32 electrons (25%)
Shell 7 (n=7) — 7s² 2 / 32 electrons (6%)

Summary

Reference for americium's electron configuration: [Rn] 5f⁷ 7s² (full: 1s²…6p⁶ 5f⁷ 7s²). Includes orbital filling table, shell breakdown, and why the half-filled 5f⁷ is especially stable.

How it works

  1. Americium's 95 electrons fill orbitals following the Aufbau principle, in order of increasing energy.
  2. Radon ([Rn], Z=86) provides the filled core: 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹⁴ 5s² 5p⁶ 5d¹⁰ 6s² 6p⁶.
  3. After the [Rn] core, the 5f sublevel fills before 6d because 5f lies lower in energy at Z=95.
  4. Seven electrons enter 5f — one per orbital (Hund's rule), creating a half-filled 5f⁷ arrangement with all spins parallel.
  5. The two remaining electrons occupy 7s², giving the ground-state configuration [Rn] 5f⁷ 7s².
  6. The half-filled 5f⁷ is exceptionally stable due to symmetric exchange energy, similar to Eu (Z=63) in the lanthanide row.

Use cases

  • Chemistry reference for students studying actinide or transuranium element configurations.
  • Understand why the half-filled 5f⁷ subshell is energetically favorable.
  • Compare americium's configuration with europium ([Xe] 4f⁷ 6s²) in the lanthanide series.
  • Verify quantum numbers and subshell counts for exam preparation.
  • Teaching aid for periodic trends, electron shielding, and Hund's rule in f-block elements.
  • Reference for nuclear chemistry and actinide series properties.

Frequently Asked Questions

Last updated: 2026-07-08 · Reviewed by Nham Vu